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  2007 Nelson W. Taylor Lecture in Materials
   
     
 
 


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The five talks at this year’s Taylor Lecture, presented by the Penn State Department of Materials Science and Engineering in memory of Nelson W. Taylor, the former head of the Penn State Department of Ceramics, were tributes to the importance of polymers and polymer research. 
The opening talks are traditionally given by Penn State faculty members, followed by the Taylor Lecture, presented by a distinguished invited guest.  This year’s faculty speakers were Ralph Colby and Qing Wang of Materials Science and Engineering, David Allara of Chemistry, and Scott Milner, an incoming member of the Chemical Engineering faculty recruited from ExxonMobil. The Taylor Lecture was delivered by Distinguished McKnight University Professor Timothy Lodge of the University of Minnesota.
Polymers in both their natural and synthetic forms are part of every facet of our daily lives – a short list includes rubber, plastics, paints, even biological polymers such as proteins and DNA. Polymers are formed from long chains of repeating units called monomers, single molecules that can combine with similar or identical molecules. Polymer research is one of four main fields of materials study in the Department of Materials Science and Engineering, along with ceramics, metals, and electronic and photonic materials.
Ralph Colby is an expert on glass-forming liquids and liquid crystalline polymers.  His talk dealt with the attempt to make polymers, which are usually insulators, more efficient for ion transport, especially in polymers used for batteries, actuators, and fuel cells.  All the solutions would seem to rely on nanostructures that allow ions to move through materials.  Success in this attempt could win someone the Nobel Prize, Colby predicted. 
Scott Milner’s research is in the area of polymer thin films.  His talk centered on the behavior of polymer thin films in relation to the glass transition temperature.  The operating temperature of a system can change the glass transition temperature, he said.  Also, the closer the material of the thin film is to the substrate, the more glassy it will be, and the closer to the free surface, the less glassy. 
For Dave Allara, the ultimate goal of studying molecules in confined geometries is to take a single molecule and have it function as a memory circuit or a switch, a research area in which he says there is still great interest, despite many failed attempts. Recently his research has involved gallium arsenide thin films for electronics.  In trying to remove surface traps that allow electrons to escape in GaAs, he determined that you cannot get rid of the traps due to the structure. “Subtle details control important device responses,” he said.
Qing Wang’s research reaches from the nanostructure of polymer materials to the macro level of device engineering.  He discussed polymer nanocomposites used for electrical energy storage, and the possibility of using compact, low cost, and high energy polymers for high density capacitors.  High temperature polymers in hybrid vehicles are an exciting area of research.   
Tim Lodge’s 2007 Taylor Lecture was a short course on block copolymers – which in their simplest form are made of two normal polymers linked end to end.  Block copolymers self-assemble in three shapes – spheres, tubes, and sheets. More complex block copolymers can be made with three or more different polymers.
The value of block copolymers lies in the ability to control their structure, length, and shape, their sensitivity to external stimuli, tolerance of component heterogeneity (which makes them commercially useful), the free-energy process of their self-assembly, and their easy scalability.  Their potential uses are in nanoscale structures for computer memory and in their ability to precisely direct the assembly of nanostructures.
Block copolymers, Lodge said, have seen a tremendous broadening of their importance as  shown by the recent increase of journal articles on the subject. This may be due to the much greater ability to control their structures over the past ten years, he hypothesized.

The Taylor Lectures have consistently attracted notable scientists, including Nobel Laureates, to speak at Penn State. Nelson W. Taylor, in whose honor the series was established in 1969, was the individual most responsible for establishing the College of Earth and Mineral Sciences as a major center for ceramic research.

 

  Dr. Timothy Lodge,
University of Minnesota
Story: Walt Mills   Photos: Mike Fleck
 
     
     
     
  2007 Taylor Lecture Speakers
 
 

TIMOTHY P. LODGE
Distinguished McKnight University Professor of Chemistry,
University of Minnesota

Hierarchical Self-assembly in Block Copolymer Micelles

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    Biography>

  RALPH COLBY
Professor of Materials Science and Engineering, Penn State

Coercing Polymer Insulators to Transport Ions:
New soft materials for actuators, batteries and fuel cells

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    Faculty profile>

  SCOTT T. MILNER
ExxonMobil Research and Engineering

Thin Glassy Polymer Films: When Soft Materials Get Hard

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  DAVID L. ALLARA
Professor of Polymer Science and Chemistry, Penn State

Assembling, Characterizing and
Utilizing Molecules in Confined Geometries

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    Faculty profile>

  QING WANG
Assistant Professor of Materials Science and Engineering, Penn State

Tailoring Dielectric Properties of Polymers and
Polymer Nanocomposites via Multi-scale Assembly

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    Faculty Profile>
 




 

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TIM LODGE BIOGRAPHY

Tim Lodge was born in Manchester, UK, in 1954, and emigrated to the US in 1968. He was naturalized in 1979. After graduating from Harvard in 1975 with a B.A. cum laude in Applied Mathematics, he began graduate research in Chemistry at the University of Wisconsin, working with Professor John Schrag. Following his PhD, completed in December of 1980, Tim spent 20 months as a National Research Council Postdoctoral Fellow at NIST, collaborating with Dr. Charles Han. Since 1982 he has been on the Chemistry faculty at Minnesota, and was promoted to Associate Professor in 1988 and Professor in 1991. In 1995 he also became Professor of Chemical Engineering & Materials Science, and in 2001 he was named a McKnight Distinguished University Professor. He was co-recipient of the 1993 George Taylor Alumni Award for excellence in research, given by the Institute of Technology at the University of Minnesota, and in 1994, he was named a Fellow of the American Physical Society. He received the Arthur K. Doolittle Award from the Polymeric Materials Science & Engineering Division of the American Chemical Society in 1998. From 1994-2000 Tim served as Regional Editor for Macromolecular Chemistry and Physics, and since 2001 he is the Editor of Macromolecules. He is currently serving, or has served, on the Editorial Boards for Macromolecules, Journal of Chemical Physics, Journal of Polymer Science, Polymer Physics Edition, International Journal of Polymer Analysis and Characterization, and Critical Reviews in Analytical Chemistry. He has served as Chair of the Division of High Polymer Physics, American Physical Society (1997-8), and as Chair of the Gordon Research Conferences on Colloidal, Macromolecular and Polyelectrolyte Solutions (1998) and Polymer Physics (2000). He has been a visiting professor at Kyoto University, Universität Mainz, the University of California at Santa Barbara, and the University of Leeds. He has authored or co-authored over 150 refereed articles in the field of polymer science, and advised or co-advised 30 PhD theses. His research interests center on the structure and dynamics of polymer liquids, including solutions, melts, blends, and copolymers, with particular emphases on rheology, diffusion, and scattering techniques.
           
 
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