Faculty Profiles
   
   
David Allara

Professor of Chemistry and
Professor of Materials Science
104 Chemistry Building
814-865-2254
allara@matse.psu.edu

Research Interests:
• Surface chemistry and physics involving preparation, properties, and   characterization of molecular and polymeric thin films, modified surfaces, and   materials interfaces
• Transport, thermodynamic, bio-response, electronic, electromagnetic and   energy conversion properties of thin films and nanoscale structures, including   carbon nanotubes
• Complex architectures by self-and directed assembly at surfaces
• Applications include microelectronics processing, molecular electronics, quantum   computing, chem.-bio sensors, energy production and conversion,   nanolithography and biocompatibility

Areas of Research:
Science interests currently are focused on surface chemistry and physics, particularly involving molecular species as one phase.  The molecular components can range from discrete small molecules to polymers and biologically relevant materials.  The research program is directed at characterization, responses and fundamental understanding of molecular and polymeric thin films, chemically and topographically modified surfaces, and materials interfaces.  Properties of interest include charge and mass transport, thermodynamic states, bio-response, electronic and electromagnetic responses and energy conversion properties.  Material forms of interest include thin films, carbon and other nanotubes; and complex architectures formed by self-and directed assembly at a variety of material surfaces.  Characterization methods include surface infrared, Raman, X-ray photoelectron, near edge X-ray absorption fine structure spectroscopy, and optical ellipsometric spectroscpies (include in-situ UHV capabilities); X-ray scattering (synchrotron), time-of-flight secondary ion mass spectrometry, ion beam scattering, quartz crystal microgravimetry, electrochemistry and scanning probe microscopy (AFM/STM, including UHV capabilities).  Approaches to a fundamental understanding of these properties include advanced quantum chemical calculations and electromagnetic modeling for both far- and near-field responses.  Recent applications include microelectronic device processing, molecular electronics, quantum computing, chemical and bio-sensors, energy production and conversion, highly energetic materials based on nanostructures, nanolithography and biocompatibility   
Technology interests currently are focused on microelectronics, including semiconductor processing and molecular electronic devices; composite materials with tailored interfaces; energy production and conversion using electromagnetic fields and nanostructures; chemical and biological sensors; biocompatibility; adhesion; and coatings. 

Technologies impacted by research:
Microelectronics; composite materials; energy production and conversion; chemical and biological sensing; biomedicine, surface coatings


Journal Articles and Publications:
1. Single Molecular Switches, Z.J. Donhauser, B.A. Mantooth, K.F. Kelly, L.A. Bumm, J.D. Monnell, J. J. Stapleton, D.L. Allara, J.M. Tour, and P.S. Weiss; Science, 292, 2303-2307(2001)

2. Nucleation and Growth of Calcium Phosphate onto Self-Assembled Templates by a Solution-Formed Critical Nucleus Mechanism: Physiological Solutions, B.J. Tarasevich, C.C. Chusuei, D.L. Allara, J.Phys.Chem.B., 2003; 107; 10367-10377

3. Nanowire-Based Molecular Monolayer Junctions: Synthesis, Assembly, and Electrical Characterization, L.T. Cai, H. Skulason, J.B. Mattzela, J.G. Kushmerick, S.K. Pollack, J. Naciri, R. Shashidhar, T.E. Mallouk, D.L. Allara and T. S. Mayer, J.Phys.Chem. B, 2004, 108, 2827-2832

4. The Interaction of Vapor-Deposited Ti and Au with Molecular Wires , A.V. Walker, T.B. Tighe, J. Stapleton, B.C. Haynie, S. Upilli, D.L. Allara, N. Winograd, Appl.Phys.Lett., 2004, 84, 4008

5. Temperature effects on conduction through a molecular junction, Y. Selzer, M.A. Cabassi, T.S. Mayer, D.L. Allara, Nanotechnology, 2004, 15, S483–S488
 
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