Venkatraman Gopalan

Venkatraman Gopalan
Professor of Materials Science and Engineering
Associate Director, Center for Optical Technologies
N-212 Millennium Science Complex
(814) 865-2910
gopalan@matse.psu.edu
http://www.mri.psu.edu/Faculty/Gopalan/

Biographical Sketch: 

Dr. Gopalan received his B.Tech. in Metallurgical Engineering from the Indian Institute of Technology, Chennai, in 1989, and his Ph.D. in Materials Science and Engineering from Cornell University in 1995. He was a postdoctoral scholar in the Electrical and Computer Engineering Department at the Carnegie Mellon University from 1995-1996, and was subsequently awarded a director funded postdoctoral fellowship at the Los Alamos National Laboratory, where he performed research on ferroelectrics and electro-optics till 1998.

He joined Pennsylvania State University as an assistant professor in December 1998, and became a full professor in 2007. He has been awarded the National Science Foundation CAEEER award (2000), Robert R. Coble Award from the American ceramics Society (2002), Corning Faculty fellowship in Ceramic Sciences (2004), National Research Council Faculty Fellowship (2004), Wilson award for excellence in research (2005), Eshbach Faculty Fellow at the Northwestern University (2007), Richard M. Fulrath award from the American ceramics Society (2009).

He is the associate director of the Center for Optical Technologies since 2003, has served on the editorial board of the Annual Reviews of Materials research since 2004, and served as the Chairman of the User Executive Committee for the Center for Nanophase Materials Science, Oak Ridge National Laboratory, in 2010-11. Gopalan has published over 150 papers, and has written five book chapters on ferroelectric complex oxides, nonlinear optics, optical metamaterials, and scanning probe microscopy.

Research Interests: 
  • Optical materials
  • Electro-optics
  • Ultrafast nonlinear optics
  • Scanning probe microscopy
  • Near-field optical imaging
  • Ferroelectrics
  • Ferromagnets
  • Semiconductors
  • Photonic crystals structures
  • Electromagnetic wave modeling
  • Phenomenological modeling
Areas of Research: 

Our research focuses on the science and technology of nonlinear optical materials.  The work straddles materials science, physics, and optical engineering. We have three areas of current interest:

  1. Multiferroics: Multiferroics are an exciting class of materials that have co-existing ferroelectricity and magnetism.   To study the coupled dynamics of electrical and magnetic domains, we are performing real-time nonlinear optical probing with simultaneous measurement of coupled properties such as magnetoelectric effect, electro-optic and magneto-optic effects, hysteresis, and dielectric spectroscopy.  The nanoscale structure of single domain walls is studied using scanning probe techniques such as piezoelectric force-, magnetic force-, nonlinear dielectric-, electric force- , and near-field scanning optical microscopies. Modeling tools include Ginzburg-Landau phenomenology, finite element method, and electromagnetic simulations.
  2. Nonlinear optical devices:  We are developing a new class of devices by integrating diverse optical functionalities, such as optical frequency conversion, beam steering, dynamic focusing, beam shaping and high-speed switching, on a single ferroelectric chip by microengineering ferroelectric domains into gratings, lenses, prisms, and other arbitrary shapes.
  3. Hybrid semiconductor-metal-oxide nanostructures:  In a recent breakthrough with Badding group (Chemistry), we have demonstrated microstructured silica optical fibers which contain hundreds of extreme aspect ratio (~105) semiconductor and metal-filled nanowires in a highly periodic array.  We are currently characterizing light guiding and nonlinear optical responses of these hybrid fibers. 

 Experimental tools include ultrafast femtosecond lasers, electro-optics and fiber optics, scanning probe microscopies, dielectric and magnetic measurements, clean room, cryogenics, and simulations based on home-written MATLAB as well as commercial codes.

Technology Impacted By Research: 

Multiferroics enable electrical control of magnetic devices, and vice versa, and dual electrical-magnetic storage media.   Nonlinear optical devices are targeted for optical communications and infrared applications.  The vision of hybrid semiconductor-metal-silica structures is all-fiber optoelectronics, where light generation, modulation and detection can be performed within a fiber.

Journal Articles and Publications: 

V. Gopalan, D. B. Litvin, “New symmetries in crystals and handed structures,” Nature Materials , DOI: 10.1038/nmat2987 (2011). http://www.nature.com/nmat/journal/vaop/ncurrent/abs/nmat2987.html
J. R. Sparks, R. He, Noel Healy, M. Krishnamurthi, A. C. Peacock, P. J.A. Sazio, V. Gopalan, and J. V. Badding, “Low loss ZnSe Optical Fiber Waveguides,” Advanced Materials, 23, 1647-1651 (2011).
A. Vasudevarao, A. N. Morozovska, I. Grinberg, S. Bhattacharya, Y. Li, S. Jesse, P. Wu, K. Seal, S. Choudhury, E.A. Eliseev, S. Svechnikov, D. Lee, S. Phillpot, L.Q. Chen, A. M. Rappe, V. Gopalan and S.V. Kalinin, “Correlated polarization switching in the proximity of a 180 degree domain wall,” Phys. Rev. B. 82, 024111 (2010).
J. H. Lee, L. Fang, E. Vlahos, X. Ke, Y. W. Jung, L. Fitting Kourkoutis, J.W. Kim, P. Ryan, T. Heeg, M. Roeckerath, V. Goian, M. Bernhagen, R. Uecker, P. C. Hammel, K. M. Rabe, S. Kamba, J. Schubert, J. W. Freeland, D. A. Muller, C. J. Fennie, P. Schiffer, V. Gopalan, E. Johnston-Halperin & D. G. Schlom, “Creating a Strong Ferroelectric Ferromagnet via Spin-Phonon Coupling,” Nature 466, 954 (2010).
I. A. Temnykh, N. F. Baril, Z. Liu, J. V. Badding, V. Gopalan, “Optical multistability in a silicon-core silica-cladding fiber,” Optics Express, 18, 5305-5313 (2010).

Gopalan
Joan Redwing
Joan M. Redwing

Joan M. Redwing
Professor of Materials Science and Engineering, Chemical Engineering & Electrical Engineering
Chair, Intercollege Graduate Degree Program in Materials Science and Engineering
101 Steidle Building
(814) 865-8665
redwing@matse.psu.edu
http://www.personal.psu.edu/jmr31/

Biographical Sketch: 

Joan M. Redwing received her B.S. in Chemical Engineering from the University of Pittsburgh and her Ph.D. in Chemical Engineering from the University of Wisconsin-Madison. She was employed as a research engineer at Advanced Technology Materials, Inc. from 1994-1999 working on metalorganic chemical vapor deposition of group III-nitride materials. Dr. Redwing joined the faculty of the Department of Materials Science and Engineering at Penn State University in 2000. She holds a joint appointment in the Department of Electrical Engineering and is a member of the Materials Research Institute. Dr. Redwing’s research interests are in the general area of electronic materials synthesis and characterization with a specific emphasis on semiconductor thin film and nanostructure fabrication by chemical vapor deposition. She currently serves as secretary of the American Association for Crystal Growth and is an associate editor for the Journal of Crystal Growth. She is a co-author on over 130 publications in refereed journals and holds 8 U.S. patents.

Research Interests: 
  • Electronic materials synthesis and characterization
  • Metalorganic vapor phase epitaxy of compound semiconductors
  • Wide bandgap materials (Group III-Nitrides and SiC)
  • Semiconductor nanowire fabrication Gas phase and surface chemistry of epitaxial growth
Areas of Research: 

Dr. Redwing’s research interests lie in the general area of electronic and optoelectronic materials synthesis and characterization with a special emphasis on chemical vapor deposition processing of semiconductor thin films and nanostructures. A current area of research focuses on the growth of semiconductor nanowires utilizing a combination of templating and directed growth techniques. This work is aimed at understanding the fundamental mechanisms of nanowire growth and the impact of nanoscale phenomena on materials synthesis. The fabrication of radial and axial nanowire heterostructures and p-n junctions is also under investigation for nanoscale device development. This research is an integral part of several multidisciplinary research team projects at Penn State which are focused on the development of nanowire-based devices for applications in microelectronics, chemical and biological sensing and solar energy conversion. The deposition of wide bandgap group III-nitride ((Al,Ga,In)N) thin films by metalorganic chemical vapor deposition is another active area of research. These materials are used in a wide variety of electronic and optoelectronic devices including high brightness light emitting diodes used in solid state lighting and high frequency/high power transistors for radar and wireless networks. The development of group III-nitride devices is often limited by film cracking which results from intrinsic and extrinsic stress due to lattice and thermal expansion mismatches between the film and substrate. The research is focused on understanding the microstructural mechanisms responsible for film stress and developing strategies to mitigate stress and film cracking. In-situ laser reflectance is used to study dynamic changes in film stress during deposition. This information is correlated to changes in film microstructure and dislocation density measured post-growth and is used to develop models of stress generation and relaxation in the group III-nitride materials system.

Technology Impacted By Research: 

Microelectronics, photovoltaics, chemical and biological sensors, light emitting diodes, high frequency/high power electronics.

Journal Articles and Publications: 
  1. "Diameter dependent growth rate and interfacial abruptness in vapor-liquid-solid Si/Si1‑xGex heterostructure nanowires," T.E. Clark, P. Nimmatoori, K.K. Lew, L. Pan, J.M. Redwing and E.C. Dickey, Nano Lett. 8 (2008) p. 1246.
  2. "Silicon nanowire photoelectrochemical cells," A.P. Goodey, S.M. Eichfeld, K.K. Lew, J.M. Redwing and T.E. Mallouk, J. Amer. Chem. Soc. 129 (2007) p. 12344.'
  3. “In-situ axially doped n-channel silicon nanowire field-effect transistors,” T.T. Ho, Y.F. Wang, S. Eichfeld, K.K. Lew, B.Z. Liu, S.E. Mohney, J.M. Redwing and T.S. Mayer, Nano Lett. X (2008) p. XX. By the time this goes to print, we should have the page information
  4. "In-situ measurement of stress generation arising from dislocation inclination in AlxGa1‑xN:Si thin films," J.D. Acord, I.C. Manning, X.J. Weng, D.W. Snyder and J.M. Redwing, Appl. Phys. Lett. 93 (2008) p. 111910.
  5. "Effect of polarity on the growth of InN films by metalorganic chemical vapor deposition," A. Jain, X.J. Weng, S. Raghavan, B.L. VanMil, T. Myers and J.M. Redwing, J. Appl. Phys. 104 (2008) p. 053112.
2Redwing

David Saint John, a 2012 MatSC grad and instructor in Penn State's College of...

May 14, 2013

Donald W. Hamer, a 1968 Penn State alumnus and 2013 recipient of the Materials Sci...

May 13, 2013

Neal Lewis, a junior performing undergraduate research in Professor Clive Randall...

May 13, 2013

The 40th Taylor Lecture was given on April 23, 2013, by P.M. Ajayan, the Benjamin...

May 13, 2013

Beecher Watson III, undergraduate student advised by Dr. Douglas Wolfe won the...

April 29, 2013

We would like to thank all who attended the awards banquet and congratulations to...

April 22, 2013

It may sound like an interesting laboratory curiosity, but researchers hope to pri...

April 12, 2013

Michael Schmitt, a graduate student working with...

March 29, 2013

Dr. Long-Qing Chen has been el...

March 28, 2013
June 7, 2013
301 Steidle at 11am
June 10, 2013
301 Steidle at 10am
June 21, 2013
301 Steidle at 9am