Assistant Professor of Materials Science and Engineering and Norris B. McFarlane F...
Dr. Hojong Kim received his B.S in Materials Science and Engineering from Seoul National University in South Korea in 2000. He earned his Ph.D. degree in Materials Science and Engineering at MIT in 2004. His doctoral research sought to identify the corrosion mechanisms of constructional alloys in high temperature and high pressure steam environments with Professor Latanision in the Uhligh Corrosion Laboratory at MIT. After graduate research, Dr. Kim worked as a senior research engineer at Samsung-Corning Precision Glass Co. Ltd to improve the process yield for thin film transistor liquid crystal display (TFT-LCD) glass manufacturing by engineering high temperature refractory materials. After five years of industrial experience, Dr. Kim returned to MIT as a post-doctoral associate and later as a research scientist to contribute to the growing need for sustainable technology. He conducted research on high temperature electrochemical processes, including molten oxide electrolysis for carbon-free iron production and liquid metal batteries for large-scale energy storage.
• Environment-friendly electrochemical processes
• Corrosion of alloys and coatings in extreme environments
• Glass melting processes and chemistry
• High temperature materials
• Electrochemical energy storage
• Molten salt electrochemistry
• Thermodynamics of alloys
Dr. Kim’s research is motivated by the need for sustainable technology development for our modern society. The primary focus of his research lies in understanding and developing electrochemical processes to meet these needs. Electrochemical methods are critical in the evolution of technology-driven society with wide applications to energy storage and conversion systems, extraction and recycling of natural resources, and corrosion science. Furthermore, electrochemical systems offer a key to understanding fundamental thermodynamic and kinetic properties of materials and interfaces. Considering the demand for energy and resources for the current and following generations, the development of environment-friendly technologies and efficient extraction/recycling processes of resources is a requirement for a sustainable society. Thus, Dr. Kim’s research interests embrace the development of environment-friendly electrochemical processes for resource extraction/recycling, the development of corrosion-resistant materials, and energy storage systems.
• Batteries and energy storage technologies
• Extractive metallurgy (Electro-metallurgy)
• Glass melting processes
• High temperature refractory alloys
• Oxidation-resistant alloys
H. Kim, D.A. Boysen, T. Ouchi, D.R. Sadoway. Calcium-bismuth electrodes for large-scale energy storage (liquid metal batteries). Journal of Power Sources, 241:239–248, 2013.
J.M. Newhouse, S. Poizeau, H. Kim, B.L. Spatocco, D.R. Sadoway. Thermodynamic properties of calcium-magnesium alloys by determined by emf measurements. Electrochimica Acta, 91: 293–301, 2013.
H. Kim, D.A. Boysen, J.M. Newhouse, B.L. Spatocco, B. Chung, P.J. Burke, D.J. Bradwell, K. Jiang, A.A. Tomaszowska, K. Wang, W. Wei, L.A. Ortiz, S.A. Barriga, S.M. Poizeau, D.R. Sadoway. Liquid metal batteries: past, present, and future. Chemical Reviews, 113(3): 2075–2099, 2013.
S. Poizeau, H. Kim, J.M. Newhouse, B.L. Spatocco, D.R. Sadoway. Determination and modeling of the thermodynamic properties of mixing of liquid calcium-antimony alloys. Electrochimica Acta, 76: 8–15, 2012.
D.J. Bradwell, H. Kim, A.H. Sirk, D.R. Sadoway. Magnesium-antimony liquid metal battery for stationary energy storage. Journal of the American Chemical Society, 134(4): 1895–1897, 2012.
H. Kim, D.A. Boysen, D.J. Bradwell, B. Chung, K. Jiang, A.A. Tomaszowska, K. Wang, W. Wei, D.R. Sadoway. Thermodynamic properties of Ca-Bi alloys determined by emf measurements. Electrochimica Acta, 60: 154–162, 2012.
H. Kim, J. Paramore, A. Allanore, D.R. Sadoway. Electrolysis of molten iron oxide with an iridium anode: The role of electrolyte basicity. Journal of the Electrochemical Society, 158(10): E101–E105, 2011.
H. Kim, D.B. Mitton, R.M. Latanision. Stress corrosion cracking of Alloy 625 in pH 2 aqueous solution at high temperature and pressure. Corrosion, 67(3): 035002, 2011.
H. Kim, D.B. Mitton, R.M. Latanision. Effect of pH and temperature on corrosion behavior of nickel-base alloys of 625 and C-276 in high temperature and pressure aqueous solutions. Journal of the Electrochemical Society, 157(5): C194–C199, 2010.
H. Kim, D.B. Mitton, R.M. Latanision. Corrosion behavior of Ni-base alloys in aqueous HCl solution of pH 2 at high temperature and pressure. Corrosion Science, 52: 801–809, 2010.
Mike Hickner received a B.S. in Chemical Engineering from Michigan Technological University (Michigan Tech) and a M.S. and Ph.D. in Chemical Engineering from Virginia Polytechnic Institute and State University (Virginia Tech). In graduate school he worked under the direction of James E. McGrath and also spent time at Los Alamos National Laboratory. Before joining Penn State as an Assistant Professor in 2007, he was a postdoc and subsequently became a staff member at Sandia National Laboratories. Professor Hickner’s research and teaching interests include all aspects of polymeric materials, polymer micro- and nano-structure, transport characterization, spectroscopy, electrochemistry, and new materials for energy applications.
Research in the Hickner group probes the connection between the molecular identity, nanophase structure, and the resulting transport properties in polymeric materials. Our activities are motivated by application-specific needs that drive fundamental investigations into new materials chemistry and demand incisive measurements of the structure and transport properties of novel materials. We characterize technologically important materials and synthesize model materials systems to probe specific structural and property questions.
A significant thrust in our group is directed towards the study of ion-containing polymers that form robust membranes and absorb water. These types of materials are the basic functional units of solid-state electrochemical systems such as fuel cells and electrolyzers and enable water treatment technologies such as nanofiltration and reverse osmosis. The binding and diffusion of the absorbed water internal to the membrane structure and the interactions between the polymer, ions, and water are important aspects of these materials which ties the transport properties to the nano-scale and molecular features.
We employ tools such as impedance spectroscopy, NMR, TEM, AFM, vibrational spectroscopy, calorimetry, and scattering to probe the structure and transport in multiphase polymeric materials. Our team is composed of a diverse group of materials scientists, chemists, and engineers with wide ranging skills in synthesis, advanced experimental technique development, and analytical analysis. Ultimately, the goal of our group’s work is to have impact on novel applications of polymer membranes and to uncover the fundamental factors that influence the structure and resulting properties of polymeric materials.
Selected from over 65 with more than 3200 citations - full list
Gross, M. L., K. R. Zavadil, M. A. Hickner, “Chemical Mapping and Electrical Conductivity of Carbon Nanotube Patterned Arrays,” J. Mater. Chem. 2011, DOI:10.1039/C1JM11107H.
Kim, S., T. Tighe, B. Schwenzer, J. Yan, J. Zhang, J. Liu, Z. Yang, M. A. Hickner, “Chemical and Mechanical Degradation of Sulfonated Poly(sulfone) Membranes in Vanadium Redox Flow Batteries,” J. Appl Electrochem. 2011, DOI:10.1007/s10800-011-0313-0.
Xie, H., T. Saito, M. A. Hickner, “Zeta Potential of Ion-Conductive Membranes by Streaming Current Measurements,” Langmuir 2011, 27(8), 4721–4727.
Mendoza, A. J., M. A. Hickner, J. Morgan, K. Rutter, C. Legzdins, “Raman Spectroscopic Mapping of the Carbon and PTFE Distribution in Gas Diffusion Layers,” Fuel Cells 2011, 11(2), 248-254.
Elabd, Y. A., M. A. Hickner, “Block Copolymers for Fuel Cells,” Macromolecules 2011, 44(1), 1-11.
Saito, T., T. H. Roberts, T. E. Long, B. E. Logan, M. A. Hickner, “Neutral Hydrophilic Cathode Catalyst Binders for Microbial Fuel Cells,” Energ. Environ. Sci. 2011, 4(3), 928-934.
Lee, D. K., T. Saito, A. J. Benesi, M. A. Hickner, H. R. Allcock, “Characterization of Water in Proton Conducting Membranes by Deuterium NMR T1 Relaxation,” J. Phys. Chem. B. 2011, 115(5), 776–783.
Vaughn, D., R. Patel, M. A. Hickner, R. E. Schaak, “Single Crystal Colloidal Nanosheets of GeS and GeSe,” J. Am. Chem. Soc. 2010, 132(43), 15170–15172.
Kim, S., J. Yan, B. Schwenzer, J. Zhang, L. Li, J. Liu, Z. Yang, M. A. Hickner, “Investigation of Sulfonated Poly(phenylsulfone) Membrane for Vanadium Redox Flow Batteries,” Electrochem. Comm. 2010, 12, 1650–1653.
Schaefer, Z. L., M. L. Gross, M. A. Hickner, R. E. Schaak, “Uniform Hollow C-Shells: Nano-Engineered Graphitic Supports for Improved Oxygen Reduction Catalysis,” Angew. Chemie Int. Ed. 2010, 49(39), 7045-704.
Moore, H. D., T. Saito, M. A. Hickner “Morphology and Transport Properties of Midblock-sulfonated Triblock Copolymers,” J. Mater. Chem. 2010, 20, 6316-6321.
Hickner, M. A., “Ion-Containing Polymers: Functional Materials for New Energy and Clean Water,” Materials Today 2010, 13(5), 34-41.
Yan, J., M. A. Hickner “Anion Exchange Membranes by Bromination of Benzylmethyl-containing Poly(sulfone)s,” Macromolecules 2010, 43, 2349–2356.
Xu, K., K. Li, C. S. Ewing, M. A. Hickner, Q. Wang, “Synthesis of Proton Conductive Polymers with High Electrochemical Selectivity,” Macromolecules 2010, 43 (4), 1692–1694.
Saito, T., H. D. Moore, M. A. Hickner, “Synthesis of Mid-block Sulfonated Triblock Copolymers,” Macromolecules 2010, 43 (2), 599-601.
Mangiagli, P. M., C. S. Ewing, K. Xu, Q. Wang, M. A. Hickner, “Dynamic Water Uptake of Flexible Ion-Containing Polymer Networks,” Fuel Cells 2009, 9(4), 432-438.
Song, Y., M. A. Hickner, S. R. Challa, R. M. Dorin, R. M. Garcia, H. Wang, Y.-B. Jiang, P. Li, Y. Qiu, F. van Swol, C. J. Medforth, J. E. Miller, T. Nwoga, K. Kawahara, W. Li, J. A. Shelnutt, “Evolution of Dendritic Platinum Nanosheets Into Ripening-Resistant Holey Sheets,” Nano Letters 2009, 9(4), 1534-1539.
T. C. Mike Chung
Professor of Materials Science and Engineering
325 Steidle Bldg.
Professor Chung obtained his B. S. in Chemistry from Chung Yuan University (Taiwan) in 1976. He came to the U. S. for his graduate study in the Department of Chemistry, University of Pennsylvania in 1979. After finishing his Ph.D work in 1982 on conducting polymers (with Professor A. J. MacDiarmid, Nobel Laureate), he spend two years as a Research Scientist at Institute for polymers and Organic Solids (with Professor Alan J. Heeger, Nobel Laureate), University of California, Santa Barbara. Between 1984 and 1989, he was a Senior Research Staff in Corporate Research, Exxon Company. In 1989 he joined the faculty of the Pennsylvania State University as an associate professor and became professor of Polymer Science in the Department of Materials Science and Engineering in 1993. He is author of about 200 professional publications, including 2 books and 45 U.S. patents.
Professor Chung is interested in the development of new polymer chemistry that can lead to new materials with unique chemical and physical properties for applications. In his recent research activities, he has been focusing on the technologies relative to energy and environmental issues. Several current research projects include (a) functionalization of polyolefins (PE, PP, EP, etc.) via the combination of metallocene catalysts and reactive comonomers and chain transfer agents to prepare polyolefins containing side-chain or chain-end functional groups, (b) synthesis of long chain branched polyolefin, including i-PP and s-PS, and studying their thin film processing, (c) studying control radical polymerization based on new functional borane/oxygen initiators to prepare functional fluoropolymers, (d) developing new energy storage technology on the polymer thin film capacitors with high energy density, high power density, and low loss, (e) studying new polyolefin-based ion conductors that show high ion conductivity, good fuel selectivity, long term stability, and cost effective, (f) investigating new polyolefin-based oil superabsorbent (oil-SAP) for oil spill recovery, (g) synthesizing boron substituted carbon (B/C) materials and doped derivatives for hydrogen storage. My group at Penn State is recognized as a leading research group in the functionalization of polyolefin and fluoropolymers with more than 180 papers and 50 US and international patents published in the past 20 years.
In light of the 2010 BP disaster in Gulf of Mexico and the 2011 Exxon oil spill in Yellowstone river, showing no effective technology for recovering oil spills and preventing pollution in the air and water, we have recently developed a new polyolefin-based oil super-absorbent polymer (oil-SAP) that exhibits high oil absorption capability (up to 50 times of its weight), fast kinetics, easy recovery from water surface, and no water absorption. The recovered oil/oil-SAP solid is suitable for regular refining process (no pollutants and no wastes). This cost effective new oil-SAP technology shall dramatically reduce the environmental impacts from oil spills and recover most of precious natural resource.
Distinguished Professor of Materials Science and Engineering, Engineering Science and Mechanics, and Mathematics
Materials Research Institute
N-321 Millennium Science Complex
(814) 863-8101 (office)
(814) 777-3442 (cell)
email@example.com or firstname.lastname@example.org
Long-Qing Chen is Distinguished Professor of Materials Science and Engineering,Engineering Science and Mechanics, and Mathematics. He received his B.S. degree in Materials Science and Engineering from Zhejiang University in China in 1982. After spending one year as an assistant instructor at Zhejiang University, he came to the United States in 1983 and received his M.S. degree in Materials Science and Engineering from the State University of New York at Stony Brook in 1985 and a Ph.D. degree in Materials Science and Engineering from the Massachusetts Institute of Technology (MIT) in 1990. After a two-year post-doc appointment with Professor Armen G. Khachaturyanat Rutgers University, he joined the faculty at Penn State as an Assistant Professor of Materials Science and Engineering in 1992. He was promoted to Associated Professor in 1998 and Professor in 2002. Professor Chen teaches undergraduate thermodynamics of materials and graduate kinetics of materials processes and also co-teaches one graduate course and one undergraduate course in computational materials science in the department. Professor Chen's main research interest is developing multiscale computational models for predicting microstructure evolution in materials using a combination of atomistic/first-principles calculations and phase-field methods. In particular, he is interested in microstructure evolution during phase transformations, grain growth, Ostwald ripening, ferroelectric and multiferroic domain switching, and coupled ionic/electronic transport in electrochemical systems. His research group collaborates actively with numerous experimental groups, applied mathematicians, and other fellow computational materials scientists and physicists as well as with more than a dozen companies and national labs. Professor Chen has published over 350 authored or co-authored papers (H-index = 51, Number of Citations >10,000), 1 patent licensed by Intel, and co-edited 3 books in the area of computational materials science of microstructures and properties. He has given more than 200 invited talks including 6 at the Gordon Research Conferences. Professor Chen's current and former graduate students have received more than 40 awards including Materials Research Society Graduate Student Gold and Silver Medal Awards, American Ceramic Society Graduate Excellence in Materials Science Awards, Acta Materialia best student paper award, Penn State Materials Research Institute best Ph.D. thesis research award, TMS Young Leader Award, etc. Professor Chen received numerous awards for his work including:
Dr. Chen’s main research interest is in the fundamental understanding of the thermodynamics and kinetics of phase transformations and mesoscale microstructure evolution in bulk solid and thin films using computer simulations. Essentially all engineering materials contain certain types of microstructures, and our success of designing new materials is largely dependent on our ability to control them. Microstructure is a general term that refers to a spatial distribution of structural features that can be phases of different compositions and/or crystal structures, or grains of different orientations, or domains of different structural variants, or domains of different electrical or magnetic polarization, as well as structural defects such as dislocations. It is the size, shape, and spatial arrangement of the local structural features that determine the physical properties of a material such as mechanical, electrical, magnetic and optical properties. For the last decade, Dr. Chen’s group at Penn State is particularly active in developing phase-field models for microstructure evolution during various materials processes including grain growth, coherent precipitation, ferroelectric domain formation, particle coarsening, domain structure evolution in thin films, phase transformation in the presence of structural defects, and effect of stress on microstructure evolution. Current research focus is on the effect of stress/strain on ferroelectric phase transitions and domain structure evolution in ferroelectric and multiferroic thin films, domain structures in ferromagnetic shape memory alloys, electrode microstructure evolution in solid oxide fuel cells and batteries, precipitate microstructure evolution in Al-, Mg-, Ti- and Ni-alloys, strain-dominated morphological evolution, effect of defects such as dislocations on microstructure evolution. Dr. Chen’s group collaborates extensively with experimentalists and with industry.
Alloy development for aerospace and automobile iapplications
Ferroelectric and ferromagnetic thin films for memory, capacitor and electromechanical system applications
Solid oxide fuel cells and batteries
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